Jorel,
The postfix way although it's a more complex text file allows you to in very granular way pick and choose what email goes where.
postfix.org/transport.5.html
Even to the extent of user@domain.com goes one place and anotheruser@domain.com goes someplace else.
The inbound message delivery option really does not do as much.
With some other GUI servers you have a bit more limited ability to pick and choose but you still can force mail both in and out to specific locations.
Even now I have a postfix server for a customer that is sending MOST email to the proper MX record. BUT, anything going to the emergency email box of one of their partners bypasses everything and gets sent straight to where they told me to send it.
Not mission critical, but still very handy to have.